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CAS: 70-55-3
分子式: C7H9NO2S
分子量: 171.22
沸点: 221℃(10
熔点: 136-140℃
中文名称: 
对磺酰胺
对甲苯磺酰胺(PTSA)
对甲苯磺酰胺
4-甲苯磺酰胺
4-甲基苯磺酰胺
英文名称: 
Benzenesulfonamide,4-methyl-
4-toluene sulfonamide
p-Toluenesulfonamide
4-Toluenesulfonamide
4-methyl-Benzenesulfonamide
4-methylbenzenesulfonamide
4-toluenesulfanamide
4-toluenesulfonic acid, amide
4-methyl-benzenesulfonamid
p-methylbenzenesulfonamide
p-toluenesulfamide
p-toluenesulfanamide
p-toluenesulfonylamide
p-tolylsulfonamide
p-tosylamide
para-toluenesulfamine
para-toluenesulfonamide
ptsa
toluene-4-sulfonamide
toluene-p-sulphonamide
tolylsulfonamide
tosylamide
p-Toluene sulfonamide
展开更多英文名
性质描述: 白色叶状结晶。熔点138.5-139℃。溶于乙醇,难溶于水和乙醚。其水合物熔点为105℃。
生产方法: 由对甲苯磺酰氯与氨水反应而得。
用途: 用于制造染料、增塑剂、树脂、涂料、消毒剂(氯胺T)、木材加工光亮剂等。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T818733MACKLIN对甲苯磺酰胺优级试剂, ≥99%57元/250g;   152元/1kg;   599元/5kg;   1099元/10kg;   展开
储存:室温
状态:白色粉末或晶体
T818734MACKLIN对甲苯磺酰胺试剂级, 98%45元/250g;   102元/1kg;   475元/5kg;   899元/10kg;   展开
储存:室温
状态:白色粉末或晶体
T0281TCIp-Toluenesulfonamide>98.0%(HPLC)(N)145元/25G;   275元/500G;   展开

基本信息

纯度/分析方法>98.0%(HPLC)(N)
分子式/分子量C7H9NO2S = 171.21
外观与形状(20℃)固体
Reaxys-RN472689
PubChem物质ID87576257
SDBS (AIST Spectral DB)2975
MDL编号MFCD00011692

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(with Total Nitrogen)min. 98.0 %
Melting point136.0 to 140.0 ℃

物性(参考值)

熔点137 ℃
沸点214 ℃/9.98 mmHg
水溶性实际上不溶
在水中的溶解度3.2 g/l   25 ℃
溶解性(可溶于)

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#XT5075000
400335J&Kp-Toluenesulfonamide98%88元/250G;   319元/1KG;   1274元/5KG;   展开

基本信息

分子式C7H9NO2S
分子量171.22
熔点134-137
闪点202
MDL编码MFCD00011692
Beilstein472689
EINECS 编号200-741-1

安全信息

图形或危害标志
提示语Warning
危险说明H319
防范说明P305+P351+P338
WGK1
RTECSXT5075000
TSCA
A12156Alfa Aesarp-Toluenesulfonamide98+%350元/250g;   538元/500g;   1793元/2500g;   6256元/10000g;   展开

应用
p-Toluene sulfonamide was used to prepare the precursor required for synthesis of ethyl 6-phenyl-1-tosyl-1,2,5,6-tetrahydropyridine-3-carboxylate. It act as a derivative of ammonia activated to alkylation by alkyl halides is exemplified by the synthesis of N-tosyl-2,3-dihydroisoindole from o-xylylene dibromide. It is a precursor of N-tosyl imines.

备注
Store in cool, dry place, in well sealed container. Store away from oxidizing agents.

基本信息

MDL
MFCD00011692

EINECS
200-741-1

分子式
C7H9NO2S

分子量
171.22

熔点
136-139°

沸点
221°/10mm

闪点
202°(395°F)

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water.

Beilstein
472689

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
XT5075000

TSCA

C14769Alfa Aesarp-Toluenesulfonamide99%589元/250g;   1491元/1kg;   5543元/5kg;   展开

基本信息

Ref#
14769

MDL
11692

分子式
C7 H9 N O2 S

分子量
171.21

闪点
202

形态
Crystalline

105902Sigma-Aldrichp-Toluenesulfonamidereagent grade, 97%324.23元/250 G;   1142.07元/1 KG;   展开

产品说明

一般描述

在FeCl3催化下,对甲苯磺酰胺可与苄基和烯丙基醇发生直链取代反应。它被用作四丁基氟化铵(TBAF)催化的乙烯基氮丙啶开环反应的亲核试剂。

应用

使用对甲苯磺酰胺可制备用于合成乙基-6-苯基-1-甲苯磺酰基-1,2,5,6-四氢吡啶-3-羧酸乙酯所需的前体。

包装

250 g in poly bottle
1 kg in poly bottle

基本信息

线性分子式CH3C6H4SO2NH2
分子量171.22
Beilstein472689
EC 号200-741-1
MDL编号MFCD00011692
PubChem化学物质编号24846713
NACRESNA.22

产品性质

质量水平100
等级reagent grade
测定98%
mp134-137 ℃ (lit.)
溶解性DMSO: soluble
SMILES stringCc1ccc(cc1)S(N)(=O)=O
InChI1S/C7H9NO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)
InChI keyLMYRWZFENFIFIT-UHFFFAOYSA-N
Gene Informationhuman ... CA1(759), CA2(760), CA5A(763), CA5B(11238)

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)395.6 °F - closed cup
闪点(C)202 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
236330Sigma-Aldrichp-ToluenesulfonamideReagentPlus®, ≥99%489.98元/10 G;   1909.54元/50 G;   展开

产品说明

一般描述

研究了氰甲基三丁基磷 (CMBP) 介导的 甲苯磺酰胺与醇的反应 。

应用

p -甲苯磺酰胺已被用作:

  • 四丁基氟化铵 (TBAF) 催化乙烯基氮丙啶开环反应中的亲核试剂
  • 己内酰胺二铑 (II) 催化烯烃氮杂环丙烷化反应的试剂

包装

10, 50 g in poly bottle

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式CH3C6H4SO2NH2
分子量171.22
Beilstein472689
EC 号200-741-1
MDL编号MFCD00011692
PubChem化学物质编号24854164
NACRESNA.22

产品性质

质量水平200
产品线ReagentPlus®
测定≥99%
mp134-137 ℃ (lit.)
SMILES stringCc1ccc(cc1)S(N)(=O)=O
InChI1S/C7H9NO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)
InChI keyLMYRWZFENFIFIT-UHFFFAOYSA-N
Gene Informationhuman ... CA1(759), CA2(760), CA5A(763), CA5B(11238)

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)395.6 °F - closed cup
闪点(C)202 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
8.08230Sigma-Aldrich4-Toluenesulfonamidefor synthesis226.45元/100 G;   416.33元/1 KG;   5358.88元/25 KG;   展开

产品说明

分析说明

Assay (HPLC, area%): ≥ 98.0 % (a/a)
Melting range (lower value): ≥ 136 °C
Melting range (upper value): ≤ 140 °C
Identity (IR): passes test

基本信息

线性分子式4-(CH3)C6H4SO2NH2
分子量171.22
MDL编号MFCD00011692
EC索引号200-741-1

产品性质

质量水平200
测定≥98.0% (HPLC)
bp220-222 ℃/13 hPa
mp136-138 ℃
转变温度flash point 202 ℃
储存温度2-30℃
InChI1S/C7H9NO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)
InChI keyLMYRWZFENFIFIT-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)395.6 °F - closed cup
闪点(C)202 ℃ - closed cup
PHR1474Supelcop-ToluenesulfonamidePharmaceutical Secondary Standard; Certified Reference Material1992.11元/500 MG;   展开

产品说明

一般描述

Pharmaceutical secondary standards for application in quality control, provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards. p-Toluenesulfonamide is widely used as a fungicide and mildewcide in paints and coatings. It is also used in resins, plasticizers, and organic synthesis.

应用

These Secondary Standards are qualified as Certified Reference Materials. These are suitable for use in several analytical applications including but not limited to pharma release testing, pharma method development for qualitative and quantitative analyses, food and beverage quality control testing, and other calibration requirements.

分析说明

These secondary standards offer multi-traceability to the USP, EP and BP primary standards, where they are available.

其他说明

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

附注

To see an example of a Certificate of Analysis for this material enter LRAA3022 in the slot below. This is an example certificate only and may not be the lot that you receive.

基本信息

线性分子式CH3C6H4SO2NH2
分子量171.22
Beilstein472689
EC 号200-741-1
MDL编号MFCD00011692
PubChem化学物质编号329823403
NACRESNA.24

产品性质

质量水平300
等级certified reference material
pharmaceutical secondary standard
CofAcurrent certificate can be downloaded
包装pkg of 500 mg
technique(s)HPLC: suitable
gas chromatography (GC): suitable
mp134-137 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
药典可追溯性traceable to USP 1672020
储存温度2-30℃
SMILES stringCc1ccc(cc1)S(N)(=O)=O
InChI1S/C7H9NO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)
InChI keyLMYRWZFENFIFIT-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
1672020USPp-ToluenesulfonamideUnited States Pharmacopeia (USP) Reference Standard5145.97元/200 MG;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia.

分析说明

These products are for test and assay use only. They are not meant for administration to humans or animals and cannot be used to diagnose, treat, or cure diseases of any kind.  ​

其他说明

USP issued SDS can be found here.
Sales restrictions may apply.

基本信息

线性分子式CH3C6H4SO2NH2
分子量171.22
Beilstein472689
MDL编号MFCD00011692
PubChem化学物质编号329751351

产品性质

等级pharmaceutical primary standard
manufacturer/tradenameUSP
mp134-137 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
SMILES stringCc1ccc(cc1)S(N)(=O)=O
InChI1S/C7H9NO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)
InChI keyLMYRWZFENFIFIT-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)395.6 °F - closed cup
闪点(C)202 ℃ - closed cup
216546Fluorochem4-Methylbenzenesulfonamide95%220元/10g;   330元/100g;   418元/500g;   展开

基本信息

CAS Number70-55-3
MDL NumberMFCD00011692
Boiling Point214℃
Melting Point137℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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