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CAS: 5056-07-5
分子式: C8H10OS
分子量: 154.23
熔点: 74-76℃
英文名称: 
s(-)-methyl p-tolyl sulfoxide
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S981719MACKLIN(S)-甲基对甲苯砜98%191元/100mg;   323元/250mg;   1102元/1g;   5159元/5g;   展开
储存:2-8°C, 密封, 干燥
339997Sigma-Aldrich(S)-(-)-Methyl p-tolyl sulfoxide99%3260.55元/1 G;   展开

产品说明

应用

(S)-(-)-Methyl p-tolyl sulfoxide can be used as a nucleophilic reagent to synthesize:

  • Optically active β-disulfoxides by reacting with arenesulfinic esters via formation of α-sulfinylcarbanion.
  • α-substituted N-hydroxylamines by treating with nitrones via preparation of (S)-(-)-methyl p-tolyl sulfoxide anion.
  • 2-O-benzyl-3,4-O-isopropylidene-L-erythrose by one-carbon homologation of 2,3-O-isopropylidene-L-glyceraldehyde.

包装

1 g in glass bottle

基本信息

线性分子式CH3C6H4S(O)CH3
分子量154.23
Beilstein2324696
MDL编号MFCD00151503
PubChem化学物质编号24860755

产品性质

质量水平100
测定99%
旋光性[α]20/D −145°, c = 2 in acetone
光学纯度ee: 99% (HPLC)
mp75-77 ℃ (lit.)
SMILES stringCc1ccc(cc1)S(C)=O
InChI1S/C8H10OS/c1-7-3-5-8(6-4-7)10(2)9/h3-6H,1-2H3/t10-/m0/s1
InChI keyFEVALTJSQBFLEU-JTQLQIEISA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
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