| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| S803261 | MACKLIN | |S|-(+)-联萘酚磷酸酯 | 97% | 28元/1g; 65元/5g; 288元/25g; 999元/100g; | 展开 |
储存：2~8°C 状态：白色固体或粉末 折射率：595 ° (C=1, MeOH) |
| B1144 | TCI | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate | >97.0%(T) | 140元/100MG; 590元/1G; | 展开 |
基本信息 | 纯度/分析方法 | >97.0%(T) | | 分子式/分子量 | C20H13O4P = 348.29 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 2014273 | | PubChem物质ID | 87564085 | | MDL编号 | MFCD00010045 |
技术规格 | Appearance | White to Almost white powder to crystal | | Optical purity(LC) | min. 98.0 ee% | | Purity(Neutralization titration) | min. 97.0 % | | Specific rotation [a]20/D | +580.0 to +605.0 deg(C=1, MeOH) | | Solubility in hot Methanol | almost transparency |
物性(参考值) |
| 109345 | J&K | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate | 98% | 165元/1G; 657元/5G; | 展开 |
基本信息 | 分子式 | C20H13O4P | | 分子量 | 348.29 | | 熔点 | 320 | | 比旋光度([α]20D) | 585° to 615° (C=1.35, MeOH) | | MDL编码 | MFCD00010045 | | Beilstein | 4787775 |
安全信息 | 图形或危害标志 |  | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P260
P281 | | WGK | 3 | | RTECS | RZ2475100 |
|
| 15-0053 | Strem | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate | min. 98% | 660元/1g; 2418元/5g; | 展开 |
Technical Notes: 1.Asymmetric hetero Diels-Alder reaction catalyzed by chiral lanthanide(IIl) complex. 2. Highly efficient Mannich reaction 3.Acidic Resolving agent for certain amine/racemic mixtures. (Ref. 3,4) References: 1.Org. L ett., 2000, 2, 49. 2.Org. L ett., 2012, 14, 2126. 3.J. Org. Chem., 1991, 56, 485. 4.US 6,162,919 |
| L14137 | Alfa Aesar | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate | 98+% | 891元/250mg; 2701元/1g; 4087元/5g; | 展开 |
应用
Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction. 备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents. 基本信息 MDL
MFCD00010045 分子式
C20H13O4P 分子量
348.30 熔点
>300° 灵敏度
Ambient temperatures. 形态
Powder 溶解性
Soluble in DMSO and methanol (hot). Beilstein
4787775 GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
否 |
| 248940 | Sigma-Aldrich | (S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate | 97% | 721.51元/1 G; 2181.49元/5 G; | 展开 |
产品说明 包装 1, 5 g in glass bottle 应用 用作不对称 Mannich 反应中手性布朗斯特酸催化剂。 基本信息 | 经验(实验)分子式 | C20H13O4P | | 分子量 | 348.29 | | Beilstein | 4787775 | | MDL编号 | MFCD00010045 | | PubChem化学物质编号 | 24854963 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 97% | | 旋光性 | [α]22/D +595°, c = 1.35 in methanol | | SMILES string | OP1(=O)Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45 | | InChI | 1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22) | | InChI key | JEHUZVBIUCAMRZ-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 | | 预防措施声明 | P302 + P352 | | 危险分类 | Skin Irrit. 2 | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
|
| 448636 | Fluorochem | (11bS)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide | 95% | 220元/1g; 484元/5g; 858元/10g; 1562元/25g; | 展开 |
基本信息 | CAS Number | 35193-64-7 | | MDL Number | MFCD00010045 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
|
|
m.cnreagent.com