CAS 35193-63-6; 联萘酚磷酸酯; 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate

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CAS:

35193-63-6

分子式:

C₂₀H₁₃O₄P

分子量:

348.29

熔点:

≥300 °C

中文名称:

联萘酚磷酸酯

英文名称:

1,1'-binaphthyl-2,2'-diyl hydrogen phosphate

1,1'-binaphthyl-2,2'-diyl hydrogen-phosphate

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

(+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate

(+/-)-2,2'-Dihydroxy-1,1'-binaphthyl Hydrogenphosphate

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

详情

B803438

MACKLIN

联萘酚磷酸酯

99%

30元/1g; 60元/5g; 280元/25g; 605元/100g; 2999元/500g;

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储存：室温
状态：白色到灰白色粉末,晶体和/或块状

B2130

TCI

(±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate

>98.0%(T)(HPLC)

700元/5G; 2005元/25G;

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基本信息

纯度/分析方法	>98.0%(T)(HPLC)
分子式/分子量	C₂₀H₁₃O₄P = 348.29
外观与形状(20℃)	固体
Reaxys-RN	2014273
PubChem物质ID	87564998
MDL编号	MFCD00010045

技术规格

Appearance	White to Yellow to Orange powder to crystal
Purity(HPLC)	min. 98.0 area%
Purity(Neutralization titration)	min. 98.0 %

H60395

Alfa Aesar

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate

99%

500元/1g; 2494元/5g;

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应用
1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

备注
Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents.

基本信息

MDL
MFCD00010045

EINECS
252-425-8

分子式
C₂₀H₁₃O₄P

分子量
348.29

灵敏度
Ambient temperatures.

形态
Solid

溶解性
Extremely low soluble in water.

安全信息

TSCA
否

292966

Sigma-Aldrich

1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

95%

740.65元/5 G;

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基本信息

经验(实验)分子式	C₂₀H₁₃O₄P
分子量	348.29
EC 号	252-425-8
MDL编号	MFCD00010045
PubChem化学物质编号	24857622
NACRES	NA.22

产品性质

质量水平	100
测定	95%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
官能团	phosphine
SMILES string	OP1(=O)Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45
InChI	1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)
InChI key	JEHUZVBIUCAMRZ-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

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