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CAS: 29490-19-5
分子式: C2H2N2S
分子量: 86.12
熔点: 185-188℃
中文名称: 
噻二唑
2-巯基-5-甲基-1,3,4-噻二唑
甲基巯基噻二唑
2-甲基-5-巯基-1,3,4-噻二唑
英文名称: 
5-Methyl-1,3,4-thiadiazole-2-thiol
2-Mercapto-5-methyl-1,3,4-thiadiazde
methyl mercapto thiadiazole
Thiadiazole
2-mercapto-5-methyl-1,3,4-thiadiazole
2-mercapto-5-methyl-1,3,4thiadiazole
1,3,4-thiadiazole
1,3,4-Thiadiazol
[1,3,4]Thiadiazole
1,3.4-Thiadiazole
性质描述: 白色结晶性粉末。熔点184℃。
生产方法: 由乙酸乙酯经肼化、加成、环合而得。将乙酸乙酯、水合肼和无水乙醇加热回流反应5h,得乙酰肼乙醇溶液。然后经冷却。加入二硫化碳,在25℃搅拌反应1h。再经冷却、静置、过滤。滤饼用无水乙醇洗涤,得N-乙酰肼基二硫代甲酸钾。低温干燥后,将其分次加入-5℃以下的浓酸中,在不超过5℃的温度下搅拌反应。然后将反应物冰析、过滤,滤饼用大量冰水洗去游离的硫酸,再经低温真空干燥,得噻二唑。
用途: 该品是抗菌素类药物头孢菌素V的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M812783MACKLIN2-巯基-5-甲基-1,3,4-噻二唑99%30元/25g;   79元/100g;   262元/500g;   1235元/2.5kg;   展开
储存:室温
状态:白色-略淡黄色晶体-粉末
M0976TCI5-Methyl-1,3,4-thiadiazole-2-thiol>98.0%(T)210元/25G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C3H4N2S2 = 132.20
外观与形状(20℃)固体
Reaxys-RN606663
PubChem物质ID87572956
SDBS (AIST Spectral DB)18940
MDL编号MFCD00038349

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %
Melting point184.0 to 188.0 ℃

物性(参考值)

熔点186 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
107325J&K2-Mercapto-5-methyl-1,3,4-thiadiazole99%60元/5G;   181元/25G;   404元/100G;   1612元/500G;   展开

基本信息

分子式C3H4N2S2
分子量132.21
熔点188-189
MDL编码MFCD00038349
Beilstein606663
EINECS 编号249-667-1

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
B21355Alfa Aesar2-Mercapto-5-methyl-1,3,4-thiadiazole99%885元/50g;   3740元/250g;   展开

基本信息

MDL
MFCD00038349

EINECS
249-667-1

分子式
C3H4N2S2

分子量
132.21

熔点
182-185°

灵敏度
Ambient temperatures.

形态
Powder

Beilstein
606663

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

PHR2437SupelcoCefazolin Impurity EPharmaceutical Secondary Standard; Certified Reference Material6146.58元/100 MG;   展开

产品说明

一般描述

Pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards

分析说明

These secondary standards offer multi-traceability to the USP, EP and BP primary standards, where they are available.

其他说明

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

附注

To see an example of a Certificate of Analysis for this material enter LRAC4535 in the Documents slot below. This is an example certificate only and may not be the lot that you receive.

基本信息

经验(实验)分子式C3H4N2S2
分子量132.21
MDL编号MFCD00038349

产品性质

等级certified reference material
pharmaceutical secondary standard
形式powder
包装pkg of 100 mg
mp188-189 ℃ (lit.)
储存温度2-8℃
SMILES stringCc1nnc(S)s1
InChI1S/C3H4N2S2/c1-2-4-5-3(6)7-2/h1H3,(H,5,6)
InChI keyFPVUWZFFEGYCGB-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
068973Fluorochem5-Methyl-1,3,4-thiadiazole-2-thiol97%286元/5g;   550元/25g;   1100元/100g;   2156元/250g;   展开

基本信息

CAS Number29490-19-5
MDL NumberMFCD00038349
Melting Point186℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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