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CAS: 2633-66-1
分子式: C9H11BrMg
分子量: 223
英文名称: 
2-Mesitylmagnesium bromide solution
2,4,6-Trimethylphenylmagnesium bromide
2-mesitylmagnesium bromide
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M914565MACKLIN2-均三甲苯基溴化镁1.0 M solution in THF, MkSeal236元/25ml;   516元/100ml;   2141元/500ml;   展开
储存:室温
状态:液体
914974J&K2-Mesitylmagnesium bromide, 1.0 M solution in THF, J&KSeal1.0 M 四氢呋喃溶液, J&KSeal瓶236元/25ML;   777元/100ML;   2980元/500ML;   展开

基本信息

分子式C9H11BrMg
分子量223.39
闪点-17
密度1.005
MDL编码MFCD00009663

安全信息

图形或危害标志
提示语Danger
危险说明H225
H314
H335
H351
防范说明P210
P261
P280
P305+P351+P338
P310
UN号码2924
危险分类3
次要危险性8
包装等级II
WGK3
227234Sigma-Aldrich2-Mesitylmagnesium bromide solution1.0 M in THF615.97元/100 ML;   4681.41元/800 ML;   展开

产品说明

应用

2-三甲基溴化镁是一种Grignard试剂,可通过动力学阻断反应性分子位点,通常用于合成稳定的芳香族化合物,如二苯并噻吩、 二茚并蒽、 萜烯 和二甲基苯基[2,1-a]芴。它还可用于各种芳族交叉偶联反应。

包装

100, 800 mL in Sure/Seal™

基本信息

线性分子式(CH3)3C6H2MgBr
分子量223.39
MDL编号MFCD00009663
PubChem化学物质编号24853266
NACRESNA.22

产品性质

质量水平100
reaction suitabilityreaction type: Grignard Reaction
浓度1.0 M in THF
密度1.005 g/mL at 25 ℃
SMILES stringCc1cc(C)c([Mg]Br)c(C)c1
InChI1S/C9H11.BrH.Mg/c1-7-4-8(2)6-9(3)5-7;;/h4-5H,1-3H3;1H;/q;;+1/p-1
InChI keyYXVSITSUDRGILL-UHFFFAOYSA-M

安全信息

象形图GHS02GHS05GHS07GHS08
警示用语:Danger
危险声明H225 - H314 - H335 - H351
预防措施声明P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
危险分类Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官Respiratory system
补充剂危害EUH014 - EUH019
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)1.4 °F - closed cup
闪点(C)-17.0 ℃ - closed cup
214215Fluorochem2,4,6-Trimethylphenylmagnesium bromide, 0.5M 2-MeTHF97%4136元/50ml;   6402元/100ml;   展开

基本信息

CAS Number2633-66-1
MDL NumberMFCD00009663
Density0.854

安全信息

图形或危害标志
危险性说明 EUH014: Reacts violently with water.
EUH019: May form explosive peroxides.
H225: Highly flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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