基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	危险
危险性说明	H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。 H350 : 可能致癌。 H410 : 对水生生物毒性极大并具有长期持续影响。 comburant puissant.
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P273 : 避免释放到环境中。 P270 : 使用本产品时不要进食、饮水或吸烟。 P202 : 在阅读并明了所有安全措施前切勿搬动。 P220 : 避开/贮存处远离服装/可燃材料。 P210 : 远离热源。 P201 : 使用前取得专用说明。 P221 : 采取一切防范措施，避免与可燃物/.?混合。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P283 : 穿防火/阻燃服装。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P391 : 收集溢出物。 P308 + P313 : 如接触到或有疑虑：求医/就诊。 P361 + P364 : 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P306 + P360 : 如沾染衣服：立即用水充分冲洗沾染的衣服和皮肤，然后脱掉衣服。 P371 + P380 + P375 : 在发生大火和大量泄漏：撤离现场。因有爆炸危险，须远距离救火。 P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P311 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。呼叫急救中心/医生。 P403 + P233 : 存放在通风良好的地方。保持容器密闭。 P405 : 存放处须加锁。

运输信息

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H272 H317 H350i H410
防范说明	P201 P220 P273 P280 P308+P313 P501
UN号码	1479
危险分类	5.1
包装等级	II
WGK	2
TSCA	是

应用
Pyridinium chlorochromate is used as an oxidizing agent to convert primary and secondary alcohols to aldehydes and ketones respectively. It is involved in the preparation of cyclohexanone, (-)-pulegone and lactones. It plays an important role in the selective mono-oxidation of xylenes to tolualdehydes and arylhydroxyamines to nitroso compounds. Furthermore, it is utilized as an oxidant for amino acids, L-cystine, aniline, cycloalkanols, vicinal and non-vicinal diols as well as in the Babler oxidation reaction.

备注
Incompatible with alcohols, acetone and methanol.

基本信息

MDL
MFCD00013106

EINECS
247-595-5

分子式
C₅H₆ClCrNO₃

分子量
215.56

熔点
ca 206° dec.

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in acetone, benzene, dichloromethane, acetonitrile and tetrahydrofuran.

Merck
14,7974

GHS危害和防范说明

GHS符号

Hazard Statements
H272-H317-H350-H400-H410
May intensify fire; oxidizer.May cause an allergic skin reaction.May cause cancer.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P221-P210a-P201-P220-P405-P501a
Take any precaution to avoid mixing with combustibles.Keep away from heat. - No smoking.Obtain special instructions before use.Keep/Store away from clothing/combustible materials.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
5.1

包装组
II

危险类别
49-8-43-50/53
May cause cancer by inhalation.Contact with combustible material may cause fire.May cause sensitization by skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
53-45-60-61
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

TSCA
是

基本信息

Ref#
18367

MDL
13106

分子式
C5 H6 Cl Cr N O3

分子量
215.56

形态
Orange cryst powder

安全信息

危险等级
5.1

包装组
II

产品说明

包装

25, 100, 500 g in glass bottle

应用

稳定的多功能氧化剂，用于醇类的温和选择性氧化。
用于由 D-葡萄糖经 Grubbs 催化闭环复分解反应合成 α,ß-不饱和内酯过程中氧化烯丙基亚甲基。

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H272 - H317 - H350i - H410
预防措施声明	P201 - P210 - P273 - P280 - P302 + P352 - P308 + P313
危险分类	Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Ox. Sol. 2 - Skin Sens. 1
储存分类代码	5.1B - Oxidizing hazardous materials
WGK	WGK 2
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H272 H317 H350i H410
防范说明	P201 P220 P273 P280 P308+P313 P501
UN号码	1479
危险分类	5.1
包装等级	II
WGK	2
TSCA	是

基本信息

安全信息

图形或危害标志
危险性说明	H271: May cause fire or explosion; strong oxidiser. H301: Toxic if swallowed. H311: Toxic in contact with skin. H331: Toxic if inhaled. H350: May cause cancer .. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects.
防范说明	P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from – No smoking. P220: Keep/Store away from clothing/./combustible materials. P221: Take any precaution to avoid mixing with combustibles/. P260: Do not breathe . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear . P281: Use personal protective equipment as required. P283: Wear . P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P306 + P360: IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. P308 + P313: IF exposed or concerned: Get medical advice/ attention. P311: Call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P361: Remove/Take off immediately all contaminated clothing. P363: Wash contaminated clothing before reuse. P370 + P378: In case of fire: Use for extinction. P371 + P380 + P375: In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P391: Collect spillage. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.