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CAS: 2576-47-8
分子式: C2H7Br2N
分子量: 204.89
熔点: 172-176℃
中文名称: 
2-溴乙胺氢溴酸盐
2-溴乙胺氢溴化物
溴乙胺氢溴酸盐
氢溴酸-2-溴乙胺
英文名称: 
2-Bromoethylamine hydrochloride
Ethanamine,2-bromo-,hydrobromide
2-bromo-ethylamin hydrobromide
2-aminoethylbromide hydrobromide
2-bromoethanamine hydrobromide
2-bromoethylamine hydrobromide
beta-bromoethylamine hydrobromide
2-bromo-ethanamin hydrobromide
bromo ethylamine,hydrobromide
2-Aminoethyl bromide hydrobromide
性质描述: 无色晶体。熔点172-174℃。易溶于水,溶于甲醇,难溶于醚。
生产方法: 由乙醇胺溴化而得。在反应锅中投入溴氢酸,冷却,搅拌下滴加乙醇胺,于半小时内滴加完毕,然后蒸出投入量85%的溴氢酸(溴氢酸的投料量是乙醇胺的8.89倍重量),约20h蒸完。浓缩液冷却至70-80℃后,将其放入预先冷冻的丙酮中,再冷却至5℃以下,过滤出结晶的2-溴乙胺氢溴酸盐。收率70%。
用途: 用作助焊剂。药物中间体,用于生产急救药物克脑迷(AET)
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B802635MACKLIN2-溴乙胺氢溴酸盐99%41元/25g;   79元/100g;   269元/500g;   1200元/2.5kg;   展开
储存:室温
状态:白色到黄色到橙色粉末,晶体和/或块状
B0591TCI2-Bromoethylamine Hydrobromide>98.0%(T)(N)100元/25G;   350元/100G;   1190元/500G;   展开

基本信息

纯度/分析方法>98.0%(T)(N)
分子式/分子量C2H6BrN・HBr = 204.89
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN3607605
PubChem物质ID87563606
MDL编号MFCD00012886

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(with Total Nitrogen)min. 98.0 %
Purity(Argentometric Titration)min. 98.0 %
Melting point173.0 to 177.0 ℃

物性(参考值)

熔点175 ℃
水溶性可溶

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。

相关法规

RTECS#KQ8225000
186686J&K2-Bromoethylamine Hydrobromide99%431元/100g;   展开

基本信息

分子式C2H6BrN·HBr
分子量204.89
熔点170-175
MDL编码MFCD00012886
Beilstein3607605
EINECS 编号219-924-2

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSKQ8225000
TSCA
A17625Alfa Aesar2-Bromoethylamine Hydrobromide98+%374元/50g;   1224元/250g;   3454元/1000g;   展开

应用
2-Bromoethylamine hydrobromide is used to construct C2-symmetric imidazolidinylidene ligands with a dioxolane backbone. It acts as a building block which is used for proteomics research. It is also used as organic and pharmaceutical intermediates for the preparation of first-aid medicines.

备注
Hygroscopic and moisture sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00012886

EINECS
219-924-2

分子式
BrCH2CH2NH2?HBr

分子量
204.90

熔点
172-176°

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water.

Beilstein
3607605

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H317-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38-43
Harmful if swallowed.Irritating to eyes, respiratory system and skin.May cause sensitization by skin contact.

安全等级
24-26-37
Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

欧盟危险品标志

RTECS
KQ8225000

TSCA

C10693Alfa Aesar2-Bromoethylamine Hydrobromide99%, ACROS Organics761元/25g;   1333元/100g;   4207元/500g;   3936元/250g;   11112元/1kg;   24210元/2.5kg;   展开

基本信息

Ref#
10693

MDL
12886

分子式
C2 H6 Br N . H Br

分子量
204.9

8.20176Sigma-Aldrich2-Bromoethylammonium bromidefor synthesis694.95元/100 G;   3215.3元/500 G;   7412.8元/5 KG;   71718.8元/50 KG;   展开

产品说明

分析说明

含量(银量法): ≥ 99.0 %
熔程(下限值): ≥ 171 °C
熔程(上限值): ≤ 176 °C
同一性(IR):通过测试

基本信息

经验(实验)分子式C2H7Br2N
分子量204.89
MDL编号MFCD00012886
EC索引号219-924-2

产品性质

质量水平200
形式crystals
效能200-2000 mg/kg LD50, oral (Rat)
pH值(酸碱度)2.9 (20 ℃, 10 g/L in H2O)
mp171-176 ℃
溶解性 >500 g/L
储存温度2-30℃
InChI1S/C2H6BrN.BrH/c3-1-2-4;/h1-2,4H2;1H
InChI keyWJAXXWSZNSFVNG-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H412
预防措施声明P264 - P270 - P273 - P301 + P312 - P501
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)142.9 °F - Pensky-Martens closed cup
闪点(C)61.6 ℃ - Pensky-Martens closed cup
B65705Sigma-Aldrich2-Bromoethylamine Hydrobromide99%467.67元/25 G;   1539.49元/100 G;   展开

产品说明

包装

25, 100 g in glass bottle

应用

用于构建具有二氧戊环主链的 C2-对称咪唑烷亚基配体。

基本信息

线性分子式BrCH2CH2NH2 · HBr
分子量204.89
Beilstein3607605
EC 号219-924-2
MDL编号MFCD00012886
PubChem化学物质编号24891920
NACRESNA.22

产品性质

质量水平200
测定99%
mp170-175 ℃ (lit.)
SMILES stringBr.NCCBr
InChI1S/C2H6BrN.BrH/c3-1-2-4;/h1-2,4H2;1H
InChI keyWJAXXWSZNSFVNG-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H412
预防措施声明P264 - P270 - P273 - P301 + P312 - P501
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)142.9 °F - Pensky-Martens closed cup
闪点(C)61.6 ℃ - Pensky-Martens closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
06670Sigma-Aldrich2-Bromoethylamine Hydrobromidepurum, ≥97.0% (AT)1273.71元/100G;   5606.9元/500G;   展开

产品说明

应用

2-溴乙胺氢溴酸盐(BEA-HBr)可用作反应物制备:

  • 氨基功能化离子液体,1-胺乙基-3-甲基咪唑六氟磷酸盐([2-aemim][PF6])。[2-aemim][PF6]可作为芳族醛、丙二腈、乙酰乙酸乙酯发生Knoevenagel缩合反应合成4H-吡喃衍生物的催化剂。
  • 通过环缩合反应合成2-(N-aryl-N-芳酰基)氨基-4,5-二氢噻唑衍生物的催化剂。

也可用作尼龙表面改性的烷基化剂,以获得伯/仲/叔胺基。

基本信息

线性分子式BrCH2CH2NH2 · HBr
分子量204.89
Beilstein3607605
EC 号219-924-2
MDL编号MFCD00012886
PubChem化学物质编号329748258
NACRESNA.22

产品性质

质量水平200
等级purum
测定≥97.0% (AT)
mp170-175 ℃ (lit.)
170-175 ℃
SMILES stringBr.NCCBr
InChI1S/C2H6BrN.BrH/c3-1-2-4;/h1-2,4H2;1H
InChI keyWJAXXWSZNSFVNG-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H412
预防措施声明P264 - P270 - P273 - P301 + P312 - P501
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)142.9 °F - Pensky-Martens closed cup
闪点(C)61.6 ℃ - Pensky-Martens closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
078524Fluorochem2-Bromoethylamine Hydrobromide98%220元/5g;   242元/25g;   616元/100g;   2046元/500g;   展开

基本信息

CAS Number2576-47-8
MDL NumberMFCD00012886
Melting Point172-178℃
Density1.581

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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