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CAS: 250611-13-3
分子式: C36H52AlClN2O2
分子量: 607.25
熔点: 250-255℃
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货号品牌产品名称规格包装、参考价格详情
13-5800Strem(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride98%2595元/1g;   10365元/5g;   展开

Technical Notes:

1Alen complexes as catalysts for the kinetic resolutonates through tandem catalysis.

2.Aluminumenthesis of bio-renewable polyesters andcycroolefins.

3.Eficiest used for the asymmetric hydrocyanation otclumulenes.

4.Catalyst used in the reaction of epoxides with heterocumlenes

References: 1.ACS Catalysis 2015, 5.3398.0 2.Chem. Commun., 2015, 51, 3.ChemCatChem 2014, 6. 2656.
531960Sigma-Aldrich(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride862.29元/1 G;   展开

产品说明

应用

Catalyst for:

  • Asymmetric iodolactonizations
  • Cyanosilylation reactions
  • Phospho-aldol catalysis

包装

1 g in glass bottle

法律信息

经 Shasun Chemicals and Drugs Limited 授权销售。

基本信息

经验(实验)分子式C36H52AlClN2O2
分子量607.24
MDL编号MFCD02684547
PubChem化学物质编号24877850
NACRESNA.22

产品性质

质量水平100
mp250-255 ℃ (lit.)
SMILES stringCC(C)(C)c1cc2\C=N\[C@@H]3CCCC[C@H]3\N=C\c4cc(cc(c4O[Al](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI1S/C36H54N2O2.Al.ClH/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;;1H/q;+3;/p-3/b37-21+,38-22+;;/t29-,30-;;/m1../s1
InChI keyKGVBCKDZFMLRMA-OHRASPNLSA-K

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 + H312 + H332
预防措施声明P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
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