CAS 24470-78-8; 碘化异丙基三苯鏻; isopropyltriphenylphosphonium iodide

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产品名称

规格

包装、参考价格

详情

I821418

MACKLIN

异丙基三苯基碘化膦

98%

30元/5g; 76元/25g; 291元/100g; 680元/250g; 2019元/1kg;

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储存：室温
状态：白色到黄色粉末,晶体,或颗粒

I0552

TCI

Isopropyltriphenylphosphonium Iodide

>98.0%(T)(HPLC)

270元/5G; 785元/25G;

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基本信息

纯度/分析方法	>98.0%(T)(HPLC)
分子式/分子量	C₂₁H₂₂IP = 432.29
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	光,湿气 (吸湿)
Reaxys-RN	3599629
PubChem物质ID	87571898
SDBS (AIST Spectral DB)	41188
MDL编号	MFCD00031595

技术规格

Appearance	White to Light yellow to Light orange powder to crystal
Purity(HPLC)	min. 98.0 area%
Purity(Nonaqueous Titration)	min. 98.0 %
Melting point	196.0 to 200.0 ℃
Solubility in Methanol	very faint turbidity

物性(参考值)

熔点

199 ℃

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

961366

J&K

Isopropyltriphenylphosphonium Iodide

98%

225元/5G; 674元/25G;

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基本信息

分子式	C₂₁H₂₂IP
分子量	432.28
熔点	194-197
MDL编码	MFCD00031595
Beilstein	3599629
EINECS 编号	246-281-5

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

A12881

Alfa Aesar

Isopropyltriphenylphosphonium Iodide

98+%

496元/10g; 2584元/50g; 4064元/100g; 8106元/250g;

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应用
Useful precursor of isopropylidene unit by Wittig reaction with aldehydes. It is also used in tandem cyclopropanation and Wittig olefination in a synthesis of chrysanthemic acid. Also employed in Wittig and cyclopropanation reactions. It is used as a reactant for total synthesis of heliananes, in the preparation of highly substituted benzene derivatives, synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents, 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents.

备注
Light sensitive and hygroscopic. Store away from oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

基本信息

MDL
MFCD00031595

EINECS
246-281-5

分子式
(CH₃)₂CHP(C₆H₅)₃I

分子量
432.29

熔点
195-198°

灵敏度
Hygroscopic. Light Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Solubility in methanol, very faint turbidity.

Beilstein
3599629

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

C13708

Alfa Aesar

Isopropyltriphenylphosphonium Iodide

98%

1467元/25g; 6248元/100g;

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基本信息

Ref#
13708

MDL
31595

分子式
C21 H22 I P

分子量
432.27

形态
White to pale yellow cryst powder

377481

Sigma-Aldrich

Isopropyltriphenylphosphonium Iodide

98%

732.99元/25 G;

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产品说明

应用

用于 Wittig 和环丙烷化反应。
Reactant for:

Total synthesis of heliananes
Preparation of highly substituted benzene derivatives
Synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents
4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents
Wittig reaction

包装

25 g in glass bottle

基本信息

线性分子式	(CH₃)₂CHP(C₆H₅)₃I
分子量	432.28
EC 号	246-281-5
MDL编号	MFCD00031595
PubChem化学物质编号	24863508
NACRES	NA.22

产品性质

质量水平	100
测定	98%
reaction suitability	reaction type: C-C Bond Formation
mp	194-197 ℃ (lit.)
SMILES string	[I-].CC(C)[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI	1S/C21H22P.HI/c1-18(2)22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-18H,1-2H3;1H/q+1;/p-1
InChI key	HHBXWXJLQYJJBW-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves