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CAS: 2251-50-5
分子式: C7ClF5O
分子量: 230.52
沸点: 158-159℃
中文名称: 
五氟苯酰氯
5-氟苯甲酰氯
五氟苯甲酰氯
英文名称: 
2,3,4,5,6-Pentafluorobenzoyl chloride
Pentafluorobenzoic acid chloride
Perfluorobenzoyl chloride
Benzoyl chloride,pentafluoro-
pentafluorobenzoyl chloride
性质描述: 该品为无色液体。沸点158℃-159℃,折光率1.4536,比重1.601。
用途: 医药、农药、液晶材料中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
P816946MACKLIN2,3,4,5,6-五氟苯甲酰氯99%39元/1g;   98元/5g;   298元/25g;   982元/100g;   4900元/500g;   展开
储存:2~8°C,干燥,密封
状态:无色到浅黄色液体
折射率:n20/D 1.453(lit.)
P0807TCIPentafluorobenzoyl Chloride>98.0%(GC)430元/5G;   1530元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C7ClF5O = 230.52
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN2054397
PubChem物质ID87574938
SDBS (AIST Spectral DB)5568
MDL编号MFCD00000657

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %
Effect test of GC derivalizationEffective as derivatization agent for 1-Pentadecanol

物性(参考值)

沸点159 ℃
比重1.67
折射率1.45

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3265
类别8
包装类别 III
监管条件代码(*)
217190J&KPentafluorobenzoyl Chloride99%355元/5G;   833元/25G;   2576元/100G;   展开

基本信息

分子式C7ClF5O
分子量230.51
沸点158-159
密度1.601
折光率(n20D)1.4520 - 1.4540
MDL编码MFCD00000657
Beilstein2054397
EINECS 编号218-842-4

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3265
危险分类8
包装等级II
WGK3
TSCA
A12420Alfa AesarPentafluorobenzoyl Chloride98%603元/5g;   1678元/25g;   5705元/100g;   展开

应用
A reagent used for deriving primary amines. 2,3,4,5,6-Pentafluorobenzoyl chloride was used for derivatization of 5-androstenediol, testosterone, estradiol , dihydrotestosterone and estrone in a study to determine their serum levels. 2,3,4,5,6-Pentafluorobenzoyl chloride was used to derivative dimethylamine(DMA) in study to develop a rapid and accurate GC-MS method for determination of DMA in human urine. It was used in a study to detect the presence of Enterobacter cloacae in cultures of Leuconostoc mesenteroide by gas chromatography/mass spectrometry.

备注
Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, Water, Alcohols, Strong bases.

基本信息

MDL
MFCD00000657

EINECS
218-842-4

分子式
C7ClF5O

分子量
230.52

沸点
158-159°

密度
1.668

折射率
1.4535

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Decomposes in water.

Beilstein
2054397

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
14-34
Reacts violently with water.Causes burns.

安全等级
8-26-30-36/37/39-45-60
Keep container dry.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Never add water to this product.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C14712Alfa AesarPentafluorobenzoyl Chloride98%999元/5g;   2645元/25g;   9340元/100g;   展开

基本信息

Ref#
14712

MDL
657

分子式
C7 Cl F5 O

分子量
230.52

密度
1.6

形态
Colorless liquid

安全信息

危险等级
8

包装组
II

103772Sigma-Aldrich2,3,4,5,6-Pentafluorobenzoyl chloride99%348.02元/1 G;   576.07元/5 G;   2012.1元/25 G;   展开

产品说明

应用

在一项研究中,使用2,3,4,5,6-五氟苯甲酰基取代氯衍生化5-雄烯酮、乙酸酮、雌酮、双氢甲状腺酮和雌酮,以测定其血清水平。为建立一种快速,准确测定人尿中二甲胺(DMA)的GC–MS方法,以2,3,4,5,6-五氟苯甲酰氯为衍生化试剂,进行了DMA衍生化研究。在一项研究中使用2,3,4,5,6-五氟苯甲酰氯,通过气相色谱/质谱法检测肠膜明串珠菌培养是否存在阴沟肠杆菌。

包装

1, 5, 25 g in ampule

基本信息

线性分子式C6F5COCl
分子量230.52
Beilstein2054397
EC 号218-842-4
MDL编号MFCD00000657
PubChem化学物质编号24846622
NACRESNA.22

产品性质

测定99%
折射率n20/D 1.453 (lit.)
bp158-159 ℃ (lit.)
密度1.601 g/mL at 25 ℃ (lit.)
SMILES stringFc1c(F)c(F)c(c(F)c1F)C(Cl)=O
InChI1S/C7ClF5O/c8-7(14)1-2(9)4(11)6(13)5(12)3(1)10
InChI keyMYHOHFDYWMPGJY-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P280 - P305 + P351 + P338 - P310
危险分类Skin Corr. 1B
补充剂危害EUH014
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
8.41331Sigma-AldrichPentafluorobenzoyl Chloridefor synthesis408.03元/5 ML;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.658 - 1.662
Identity (IR): passes test

基本信息

经验(实验)分子式C7ClF5O
分子量230.52
MDL编号MFCD00000657
EC索引号218-842-4

产品性质

质量水平200
测定≥98.0% (GC)
bp158-159 ℃/1013 hPa
密度1.664 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C7ClF5O/c8-7(14)1-2(9)4(11)6(13)5(12)3(1)10
InChI keyMYHOHFDYWMPGJY-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
危险分类Skin Corr. 1B
补充剂危害EUH014
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
001351FluorochemPentafluorobenzoyl Chloride95%308元/1g;   440元/5g;   660元/25g;   2266元/100g;   展开

基本信息

CAS Number2251-50-5
MDL NumberMFCD00000657
Boiling Point158-159℃
Density1.601

安全信息

图形或危害标志
危险性说明 EUH014: Reacts violently with water.
H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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