CAS 2089424-10-0; (S)-n-(1-([1,1'-联苯]-2-基)-2-(二苯基膦基)乙基)-3,5-二(三氟甲基)苯甲酰胺; (S)-n-(1-([1,1'-biphenyl]-2-yl)-2-(diphenylphosphanyl)ethyl)-3,5-bis(trifluoromethyl)benzamide

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CAS:

2089424-10-0

分子式:

C₃₅H₂₆F₆NOP

分子量:

621.55

中文名称:

(S)-n-(1-([1,1'-联苯]-2-基)-2-(二苯基膦基)乙基)-3,5-二(三氟甲基)苯甲酰胺

英文名称:

(S)-n-(1-([1,1'-biphenyl]-2-yl)-2-(diphenylphosphanyl)ethyl)-3,5-bis(trifluoromethyl)benzamide

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货号

品牌

产品名称

规格

包装、参考价格

详情

N938818

MACKLIN

N-[(1S)-1-[1,1'-联苯]-2-(二苯基膦)乙基]-3,5-二(三氟甲基)苯甲酰胺

95%

194元/5mg; 704元/25mg; 2032元/100mg;

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储存：室温，惰性气体

9026020

J&K

(S)-N-(1-([1,1'-Biphenyl]-2-yl)-2-(diphenylphosphanyl)ethyl)-3,5-bis(trifluoromethyl)benzamide

97%

3200元/100MG;

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基本信息

分子式	C₃₅H₂₆F₆NOP
分子量	621.55
比旋光度([α]20D)	-43.0° (c = 0.33, CHCl3)

15-8506

Strem

N-[(1S)-1-[1,1'-Biphenyl]-2-yl-2-(diphenylphosphino)ethyl]-3,5-bis(trifluoromethyl)-benzamide

95%

2910元/50mg;

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Technical Notes:

1.Organocatalyst used in aza-4+2 cycloaddition of N-sulfonyl-1-aza-1,3-dienes with vinyl ketones.

2.Catalyst for the enantioselective 3+2 cycloadditions of v-substituted allenoates with ß-perfluoroalkyl

enones.

3.Catalyst for asymmetric intermolecular cross Rauhut-Currier reaction of ß-perfluoroalkyl-substituted enones and vinyl ketones.

References:

1.Org. L ett. 2017, 19, 1 710.

2.Chem. Sci., 201 7, 8, 4660.

3.Adv. Synth. Catal. 201 7, 359, 3347 .

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