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CAS: 204841-19-0
分子式: C8H9BO3
分子量: 163.97
熔点: 204-208 °C(lit.)
中文名称: 
3-乙酰基苯硼酸
英文名称: 
3-Acetylbenzeneboronic acid
3'-Boronoacetophenone
3-ACETYLPHENYLBORONIC ACID
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A800104MACKLIN3-乙酰基苯硼酸96%29元/1g;   113元/5g;   447元/25g;   1586元/100g;   展开
储存:2~8°C
状态:白色到淡黄色粉末
A1942TCI3-Acetylphenylboronic Acid (contains varying amounts of Anhydride)390元/5G;   1590元/25G;   展开

基本信息

分子式/分子量C8H9BO3 = 163.97
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN8255673
PubChem物质ID87558888
SDBS (AIST Spectral DB)51605
MDL编号MFCD01074678

技术规格

AppearanceWhite to Yellow powder to crystal
Purity(Neutralization titration)95.0 to 112.0 %

物性(参考值)

熔点208 ℃
水溶性不溶
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
233361J&K3-Acetylphenylboronic acid98%65元/1G;   221元/5G;   991元/25G;   展开

基本信息

分子式C8H9BO3
分子量163.97
熔点204-208
MDL编码MFCD01074678
Beilstein8255673
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
B23478Alfa Aesar3-Acetylbenzeneboronic acid97%937元/1g;   1492元/5g;   6415元/25g;   展开

基本信息

MDL
MFCD01074678

EINECS
000-000-0

分子式
C8H9BO3

分子量
163.97

熔点
ca 200-205°

形态
Powder

Beilstein
8255673

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

470813Sigma-Aldrich3-Acetylphenylboronic acid≥95%423.35元/5 G;   2010.97元/25 G;   展开

产品说明

应用

3-Acetylphenylboronic acid can be used as a substrate:

  • In the synthesis of symmetric biaryls via oxidative dimerization using a palladium catalyst and water as a solvent.
  • In the synthesis of aryl fluorides through electrophilic fluorination reaction using acetyl hypofluorite.
  • In the coupling reactions of organoboranes with olefins using molecular oxygen and palladium catalyst.

包装

5, 25 g in glass bottle

基本信息

线性分子式CH3COC6H4B(OH)2
分子量163.97
MDL编号MFCD01074678
PubChem化学物质编号24870685

产品性质

质量水平100
测定≥95%
杂质<10% 3-acetylphenylboronic anhydride
mp204-208 ℃ (lit.)
SMILES stringCC(=O)c1cccc(c1)B(O)O
InChI1S/C8H9BO3/c1-6(10)7-3-2-4-8(5-7)9(11)12/h2-5,11-12H,1H3
InChI keySJGGDZCTGBKBCK-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
021605Fluorochem3-Acetylphenylboronic acid97%220元/1g;   286元/5g;   506元/10g;   1188元/25g;   4488元/100g;   展开

基本信息

CAS Number204841-19-0
MDL NumberMFCD01074678
Melting Point204-208℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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