| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| R817207 | MACKLIN | 醋酸铑(II)二聚体 | Rh: 43.0%-46.6% | 2198元/250mg; 6675元/1g; | 展开 |
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| R837100 | MACKLIN | 醋酸铑(II)二聚体 | 99.99% metals basis, Rh 46.2% 最低 | 2398元/250mg; | 展开 |
储存：室温 状态：绿色到深绿色粉末,晶体,颗粒,块状 |
| R0069 | TCI | Rhodium(II) Acetate Dimer | | 785元/100MG; 6990元/1G; | 展开 |
基本信息 | 分子式/分子量 | C8H12O8Rh2 = 441.99 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 14201302 | | PubChem物质ID | 87575627 | | MDL编号 | MFCD00003538 |
技术规格 | Appearance | Green to Dark green powder to crystal | | Elemental analysis(Carbon) | 20.50 to 22.70 % |
物性(参考值) 相关法规 |
| 45-1730 | Strem | Rhodium(II) Acetate Dimer | 99% | 2363元/100mg; 9454元/500mg; 28360元/2g; | 展开 |
Technical Notes: 1. Catalyst for insertion into c-H and X-H bonds. 2.Catalyst for Ylide generation. 3.Doyle-Kirmse Reaction of Allylic 4.Sulfides with DiazoalkaneClaisen rearrangement.. 5Epoxides from aldehydes. 6. Synthesis of aziridines from allylic N-tosyloxycarbamates 7.Rh/NHC catalyzed direct intermolecular arylation of C-H bonds. 8.Chiral Bronsted acid-Rh catalyzed three component reactions of diazo compounds with alcohols and imines. 9. Rh-catalyzed cyclopropenations of ynamides . 10.Tandem asymmetric aza-Darzens/ring-opening reactions . |
| L15152 | Alfa Aesar | Rhodium(II) acetate | dimer, 98+% | 0元/100mg; 0元/500mg; 0元/2g; | 展开 |
应用
Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving ?-diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds. 备注
Stable under normal conditions. 基本信息 MDL
MFCD00003538 EINECS
240-084-8 分子式
C8H12O8Rh2 分子量
441.99 熔点
205° 灵敏度
Store under Nitrogen. Ambient temperatures. 形态
Powder 溶解性
Soluble in aqueous solution like water. Slightly soluble in ethanol 安全信息 RTECS
VI9361000 TSCA
否 |
| 010560 | Alfa Aesar | Rhodium(II) acetate | dimer, Premion庐, 99.99% (metals basis), Rh 46.2% min | 0元/0.25g; 0元/1g; 0元/5g; | 展开 |
应用
Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving ?-diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds. 备注
Stable under normal conditions. 基本信息 MDL
MFCD00003538 EINECS
240-084-8 分子式
C8H12O8Rh2 分子量
441.99 熔点
205° 灵敏度
Store under Nitrogen. Ambient temperatures. 形态
Powder 溶解性
Soluble in aqueous solution like water. Slightly soluble in ethanol 安全信息 RTECS
VI9361000 TSCA
否 |
| C26863 | Alfa Aesar | Rhodium(II) Acetate Dimer | anhydrous, ca 46% Rh | 4116元/250mg; 15817元/1g; 63769元/5g; | 展开 |
基本信息 Ref#
26863 MDL
3538 分子式
C8 H12 O8 Rh2 分子量
441.98 形态
Powder |
| 209058 | Sigma-Aldrich | Rhodium(II) Acetate Dimer | powder | 1073.33元/50 MG; 3084.81元/250 MG; 11560.8元/1 G; 18034.5元/2 G; 143110元/25 G; | 展开 |
产品说明 包装 1, 2, 25 g in glass bottle
50, 250 mg in glass bottle
无底玻璃瓶。内容物在插入式融锥内。 应用 形成叶立德的有效催化剂。
用于β-羟基-α-芳基丙烯酸酯的有效合成，涉及重氮酯的分解,并伴随1,2-芳基迁移。
均相催化剂。 基本信息 | 线性分子式 | Rh2(OOCCH3)4 | | 分子量 | 441.99 | | EC 号 | 240-084-8 | | MDL编号 | MFCD00003538 | | PubChem化学物质编号 | 24852229 | | NACRES | NA.22 |
产品性质 | 形式 | powder | | 质量水平 | 200 | | reaction suitability | core: rhodium
reagent type: catalyst | | SMILES string | CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O | | InChI | 1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4 | | InChI key | SYBXSZMNKDOUCA-UHFFFAOYSA-J |
安全信息 | 象形图 |  | | 警示用语： | Warning | | 危险声明 | H315 - H319 | | 预防措施声明 | P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 482285 | Sigma-Aldrich | Rhodium(II) Acetate Dimer | 99.9% trace metals basis | 3450.57元/250 MG; 9617.7元/1 G; | 展开 |
产品说明 包装 250 mg in amber poly bottle
1 g in amber poly bottle 应用 形成叶立德的有效催化剂。
Rh 介导的 C-H 活化催化剂 基本信息 | 线性分子式 | Rh2(OOCCH3)4 | | 分子量 | 441.99 | | EC 号 | 240-084-8 | | MDL编号 | MFCD00003538 | | PubChem化学物质编号 | 24871707 | | NACRES | NA.23 |
产品性质 | 质量水平 | 100 | | 测定 | 99.9% trace metals basis | | 形式 | powder | | SMILES string | CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O | | InChI | 1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4 | | InChI key | SYBXSZMNKDOUCA-UHFFFAOYSA-J |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 - H319 | | 预防措施声明 | P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 048599 | Fluorochem | Rhodium(II)acetate dimer | 98% | 2376元/250mg; 5170元/1g; 22550元/5g; | 展开 |
基本信息 | CAS Number | 15956-28-2 | | MDL Number | MFCD00003538 | | Melting Point | >100℃ |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
| | 防范说明 | P264: Wash hands thoroughly after handling.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
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