CAS 130296-28-5; 双(1,5-环辛二烯)铑(i)六氟化锑盐; bis(1,5-cyclooctadiene)rhodium(i) hexafluoroantimonate

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产品名称

规格

包装、参考价格

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I784615

MACKLIN

双(1,5-环辛二烯)铑(I)六氟化锑盐

98%

818元/100mg; 1263元/250mg; 4362元/1g;

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储存：-20°C, 密封, 惰性气体

045523

Alfa Aesar

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

0元/250mg; 0元/1g;

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基本信息

MDL
MFCD11113031

分子式
C₁₆H₂₄F₆RhSb

分子量
555.01

形态
Crystalline powder

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H332-H401-H411
Harmful if swallowed.Harmful if inhaled.Toxic to aquatic life.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P264-P270-P304+P340-P301+P312a-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wash thoroughly after handling.Do not eat, drink or smoke when using this product.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
20/22-51/53
Harmful by inhalation and if swallowed.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
61
Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

TSCA
否

701629

Sigma-Aldrich

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

97%

1475.89元/250 MG; 5608.39元/1 G;

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产品说明

应用

Catalyst for:

[3+2] Cycloaddition
Preparation of diastereomeric chiral phosphorus mon- and bidentate diamidophosphite ligands based on dianydromannitol and their use in asymmetric metallocomplex catalysis
C-C bond-forming hydrogenation

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式	C₁₆H₂₄F₆RhSb
分子量	555.02
MDL编号	MFCD11113031
PubChem化学物质编号	329762310
NACRES	NA.22

产品性质

质量水平	100
测定	97%
形式	powder
reaction suitability	core: rhodium reagent type: catalyst
mp	58-60 ℃
储存温度	−20℃
SMILES string	[Rh+].F[Sb-](F)(F)(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2
InChI	1S/2C8H12.6FH.Rh.Sb/c21-2-4-6-8-7-5-3-1;;;;;;;;/h21-2,7-8H,3-6H2;61H;;/q;;;;;;;;+1;+5/p-6/b22-1-,8-7-;;;;;;;;
InChI key	BROZUPPJWNODCU-SXGOCSEPSA-H

安全信息

象形图
警示用语：	Warning
危险声明	H302 + H332 - H411
预防措施声明	P261 - P264 - P270 - P273 - P301 + P312 - P304 + P340 + P312
危险分类	Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)