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CAS: 104091-08-9
分子式: C24H27NO6
分子量: 425.48
熔点: 83-89 °C
英文名称: 
Fmoc-D-glutamic acid 5-tert,-butyl ester
fmoc-d-glu(otbu)-oh
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储存:2~8°C
状态:白色到浅黄色粉末
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基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C24H27NO6 = 425.48
外观与形状(20℃)固体
储存温度0-10℃
应避免的情况加热
Reaxys-RN3636375
PubChem物质ID125307829
MDL编号MFCD00077055

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %(calcd.on anh.substance)
Melting point90.0 to 94.0 ℃
Specific rotation [a]20/D+7.0 to +10.0 deg(C=1, MeOH)
Watermax. 6.0 %

物性(参考值)

熔点92 ℃
比旋光度 [α]D9° (C=1,MeOH)
溶解性(可溶于)甲醇
371623J&KFmoc-D-Glu(OtBu)-OH99%122元/1G;   425元/5G;   1722元/25G;   展开

基本信息

分子式C24H27NO6
分子量425.47
熔点83-89
比旋光度([α]20D)+3.5 to +5.5 (C=1, acetic acid: water=4:1)
MDL编码MFCD00077055
存储条件Store at 2-8℃

安全信息

防范说明P262
WGK3
H66624Alfa AesarN-Fmoc-D-glutamic acid 5-tert-butyl ester98%1050元/5g;   5661元/25g;   展开

应用
It is an important raw material and intermediate used in organic synthesis, agrochemicals and dyestuff.

备注
Refrigerate. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

基本信息

MDL
MFCD00077055

分子式
C24H27NO6

分子量
425.48

熔点
83-89°

灵敏度
Keep Cold.

形态
Solid

溶解性
Slightly soluble in water.

安全信息

TSCA

07697Sigma-AldrichFmoc-D-Glu(OtBu)-OH≥98.0% (HPLC)392.05元/1 G;   1372.37元/5 G;   展开

基本信息

经验(实验)分子式C24H27NO6
分子量425.47
MDL编号MFCD00077055
eCl@ss32160406
PubChem化学物质编号329748508
NACRESNA.26

产品性质

质量水平100
测定≥98.0% (HPLC)
形式powder
旋光性[α]/D +4.5±1, c = 1 in acetic acid: water (4:1)
reaction suitabilityreaction type: Fmoc solid-phase peptide synthesis
颜色 white
mp86-96 ℃
application(s)peptide synthesis
官能团Fmoc
储存温度2-8℃
SMILES stringCC(C)(C)OC(=O)CC[C@@H](NC(=O)OCC1c2ccccc2-c3ccccc13)C(O)=O
InChI1S/C24H27NO6/c1-24(2,3)31-21(26)13-12-20(22(27)28)25-23(29)30-14-19-17-10-6-4-8-15(17)16-9-5-7-11-18(16)19/h4-11,19-20H,12-14H2,1-3H3,(H,25,29)(H,27,28)/t20-/m1/s1
InChI keyOTKXCALUHMPIGM-HXUWFJFHSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
M03413FluorochemFmoc-D-Glu(OtBu)-OH.H2O95%286元/1g;   682元/5g;   3190元/25g;   9526元/100g;   展开

基本信息

CAS Number104091-08-9
MDL NumberMFCD00077055

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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