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CAS: 102308-32-7
分子式: C11H19NO4
分子量: 229.28
沸点: 83℃(1 to
英文名称: 
tert-butyl (S)-(-)-4-formyl-2,2-dimethyl-3-oxazol
用途: 功能金属配合物配体
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S867054MACKLIN(S)-(-)-3-(叔丁氧羰基)-4-甲酰-2,2-二甲基-1,3-噁唑烷95%61元/200mg;   145元/1g;   569元/5g;   2209元/25g;   7500元/100g;   展开
储存:2-8°C
状态:无色-淡黄色液体
B1759TCI(S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine>95.0%(GC)750元/1G;   3250元/5G;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C11H19NO4 = 229.28
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,加热
Reaxys-RN3591324
PubChem物质ID87564654
MDL编号MFCD00209557

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 95.0 %
Specific rotation [a]20/D-85.0 to -98.0 deg(C=1, CHCl3)

物性(参考值)

沸点97 ℃/1.5 mmHg
闪点107 ℃
比重1.06
比旋光度 [α]D-91.5° (C=1,CHCl3)
折射率1.45

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
432741Sigma-Aldrich(S)-(-)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde95%479.58元/1 G;   展开

产品说明

包装

1 g in glass bottle

应用

广泛应用于天然产物的不对称合成。

基本信息

经验(实验)分子式C11H19NO4
分子量229.27
Beilstein3591324
MDL编号MFCD00209557
PubChem化学物质编号24867096
NACRESNA.22

产品性质

质量水平100
测定95%
旋光性[α]20/D −90°, c = 1 in chloroform
折射率n20/D 1.445 (lit.)
bp83-88 ℃/1 mmHg (lit.)
密度1.06 g/mL at 25 ℃ (lit.)
SMILES string[H]C(=O)[C@@H]1COC(C)(C)N1C(=O)OC(C)(C)C
InChI1S/C11H19NO4/c1-10(2,3)16-9(14)12-8(6-13)7-15-11(12,4)5/h6,8H,7H2,1-5H3/t8-/m1/s1
InChI keyPNJXYVJNOCLJLJ-MRVPVSSYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)226.4 °F - closed cup
闪点(C)108 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
034478Fluorochem(S)-4-Formyl-2,2-dimethyl-oxazolidine-3-carboxylic tert-butyl ester98%1848元/1g;   7128元/5g;   13750元/10g;   30800元/25g;   展开

基本信息

CAS Number102308-32-7
MDL NumberMFCD00209557
Boiling Point97℃
Density1.06

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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