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CAS: 100-76-5
分子式: C7H13N
分子量: 111.18
沸点: 149.5ºC at 760 mmHg
熔点: 157-160℃
英文名称: 
1,4-ethylidinepiperidine
Chinuclidin
1-Azabicyclo[2.2.2]octan
1-Aza-bicyclo[2.2.2]octane
1-azabicyclo(2.2.2)octane
1,4-ethanopiperidine
1,4-ethylenepiperidine
1-azabicyclo[2.2.2]octane
quinuclidine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
Q823749MACKLIN奎宁环96%30元/50mg;   48元/250mg;   161元/1g;   801元/5g;   展开
储存:室温
状态:白色到淡黄色固体
折射率:1.512
Q0062TCIQuinuclidine>96.0%(GC)(T)425元/200MG;   1485元/1G;   6590元/5G;   展开

基本信息

纯度/分析方法>96.0%(GC)(T)
分子式/分子量C7H13N = 111.19
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN103111
PubChem物质ID253660222
Merck Index (14)8081
MDL编号MFCD00006690

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 96.0 %
Purity(Neutralization titration)min. 96.0 %

物性(参考值)

水溶性可溶

安全信息

图形或危害标志
信号词危险
危险性说明H310 : 皮肤接触致命。
H301 : 吞咽会中毒。
H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P262 : 严防进入眼中、接触皮肤或衣服。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P302 + P352 + P310 : 如皮肤沾染:用水充分清洗。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

相关法规

RTECS#CL5594625

运输信息

UN编号UN2811
类别6.1
包装类别 II
监管条件代码(*)
H54498Alfa AesarQuinuclidine97+%1445元/250mg;   4508元/1g;   11267元/5g;   展开

应用
Quinuclidine acts as a catalyst, a chemical building block and is used in organic synthesis. It is employed to prepare quinine and alkaloids. It finds application as a ligand, which is useful in the studies of OsO4-catalyzed dihydroxylation of olefins. It plays an important role in the formation of onium salts used testing of PAC-antagonist activity.

备注
Air sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents and chloroformates.

基本信息

MDL
MFCD00006690

EINECS
202-887-1

分子式
C7H13N

分子量
111.19

熔点
157-160°

灵敏度
Air Sensitive. Ambient temperatures.

形态
Solid

溶解性
Soluble in alcohol, diethyl ether, water and organic solvents.

Beilstein
103111

Merck
14,8081

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H310-H315-H318
Toxic if swallowed.Fatal in contact with skin.Causes skin irritation.Causes serious eye damage.

Precautionary Statements
P262-P280-P301+P310a-P305+P351+P338-P405-P501a
Do not get in eyes, on skin, or on clothing.Wear protective gloves/protective clothing/eye protection/face protection.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

UN#
UN2928

危险等级
6.1

包装组
II

危险类别
24/25-38-41
Toxic in contact with skin and if swallowed.Irritating to skin.Risk of serious damage to eyes.

安全等级
20-26-27-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take off immediately all contaminated clothing.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

RTECS
CL5594625

TSCA

197602Sigma-AldrichQuinuclidine97%1714.45元/1 G;   8700.44元/10 G;   展开

基本信息

经验(实验)分子式C7H13N
分子量111.18
Beilstein103111
EC 号202-887-1
MDL编号MFCD00006690
PubChem化学物质编号24851837
NACRESNA.22

产品性质

蒸汽压1.5 mmHg ( 20 ℃)
质量水平100
测定97%
mp157-160 ℃ (lit.)
溶解性H2O: very slightly soluble
H2O: very soluble
alcohol: miscible
diethyl ether: miscible
organic solvents: very soluble
SMILES stringC1CN2CCC1CC2
InChI1S/C7H13N/c1-4-8-5-2-7(1)3-6-8/h7H,1-6H2
InChI keySBYHFKPVCBCYGV-UHFFFAOYSA-N
Gene Informationrat ... Chrm1(25229)

安全信息

象形图GHS05GHS06
警示用语:Danger
危险声明H301 - H310 - H315 - H318
预防措施声明P262 - P280 - P301 + P310 + P330 - P302 + P352 + P310 - P305 + P351 + P338 + P310
危险分类Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2
储存分类代码6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
386780FluorochemQuinuclidine95%682元/200mg;   2332元/1g;   7920元/5g;   展开

基本信息

CAS Number100-76-5
MDL NumberMFCD00006690
Boiling Point198.35℃
Melting Point157-160℃
Density0.8928

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H310: Fatal in contact with skin.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P350: IF ON SKIN: Gently wash with plenty of soap and water.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P361: Remove/Take off immediately all contaminated clothing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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